Journal
SYNTHESIS-STUTTGART
Volume -, Issue 9, Pages 1353-1358Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2004-822396
Keywords
chiral phosphine ligand; chiral phosphetane derivative; rhodium complex; asymmetric hydrogenation; phosphine-borane
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(1S, 1'S, 2R, 2'R)-1,1'-Di-tert-butyl-2,2'-diphosphetanyl was prepared from tert-butylphosphine via phosphine-boranes as intermediates. The rhodium complex of the ligand was used as a highly efficient catalyst in asymmetric hydrogenations of alpha-acetylaminoacrylates and alpha-substituted enamides.
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