Journal
TETRAHEDRON
Volume 60, Issue 26, Pages 5539-5543Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.05.003
Keywords
microwave irradiation; ortho-alkylation; Wilkinson catalyst; solvent-free procedure; aromatic imines
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The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (1) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines. (C) 2004 Elsevier Ltd. All rights reserved.
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