Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 12, Pages 1388-1389Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b400562g
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A new advantageous cyanating agent, potassium hexacyanoferrate(II), is described for the palladium-catalyzed cyanation of aryl halides. All cyanide ions on the iron(II) center can be transferred to the aryl halide using palladium(II) acetate and dppf as the catalyst. Under optimized reaction conditions good yields of benzonitriles and unprecedented catalyst productivities are observed.
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