4.7 Article

Unique photoreactivity of mercury(II) 5,10,15,20-tetrakis (4-sulfonatophenyl)porphyrin

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 7, Pages 854-857

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2004.05.004

Keywords

photophysics; photochemistry; charge transfer; dissociation; metalloporphyrin; mercury

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Deviating from coplanar metalloporphyrins, the photochemistry of the kinetically labile, sitting-atop mercury(II) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin complex is characterized by irreversible porphyrin ligand to metal charge transfer and reversible dissociation. (C) 2004 Elsevier B.V. All rights reserved.

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