In situ DRIFTS investigation on the SCR of NO with NH3 over V2O5 catalyst supported by activated semi-coke

3 wt.% of V2O5 is loaded onto the activated semi-coke (V2O5/ASC) via impregnation method and used for low temperature selective catalytic reduction (SCR) of NOX with NH3. The prepared V2O5/ASC catalyst yields an over 90% NO conversion rate with excellent N-2 selectivity at 250 degrees C with a space velocity of 12,000 h(-1). The adsorption state of different species and reaction behaviors under various conditions are systematically examined with in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS). It is evidenced that NH3 and NO are absorbed on different active sites over the V2O5/ASC catalyst. At the reaction temperature (200 degrees C) in this study, NH3 is mainly absorbed on the Lewis acid sites provided by V2O5, and NO is mainly absorbed on the active sites originated from the support ASC. In addition, the NH3-SCR process takes place according to two pathways, including reaction between the coordinated NH3 and gaseous NO (E-R mechanism), and reaction between the absorbed NO2 and coordinated NH3 (L-H mechanism). The latter one plays a primary role for the improved low-temperature SCR performance of V2O5/ASC catalyst. (C) 2014 Elsevier B.V. All rights reserved.