Journal
MINI-REVIEWS IN ORGANIC CHEMISTRY
Volume 1, Issue 3, Pages 233-247Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570193043403235
Keywords
phosphorus; ligand; P-chirogenic; borane; chiral; asymmetric synthesis
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Chiral phosphorus(III) ligands with chirality residing on the phosphorus atom have seen a renaissance upon the discovery that coordination to boron stabilises the phosphorus atom towards both oxidation and racemization. In this review we describe the newer methods that are available for the preparation of P-chirogenic ligands and discuss their advantages and limitations.
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