Journal
APPLIED SURFACE SCIENCE
Volume 308, Issue -, Pages 306-310Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2014.04.160
Keywords
Direct carbonization; MOFs; Porous carbon; Supercapacitor
Categories
Funding
- Fundamental Research Funds for the Central Universities [2014QNA29]
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Three porous carbons were prepared by direct carbonization of HKUST-1, MOF-5 and Al-PCP without additional carbon precursors. The carbon samples obtained by carbonization at 1073 K were characterized by XRD, TEM and N-2 physisorption techniques followed by testing for electrochemical performance. The BET surface areas of the three carbons were in the range of 50-1103 m(2)/g. As electrode materials for supercapacitor, the MOF-5 and Al-PCP derived carbons displayed the ideal capacitor behavior, whereas the HKUST-1 derived carbon showed poor capacitive behavior at various sweep rates and current densities. Among those carbon samples, Al-PCP derived carbons exhibited highest specific capacitance (232.8 F/g) in 30% KOH solution at the current density of 100 mA/g. (C) 2014 Elsevier B.V. All rights reserved.
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