4.7 Article

Asymmetric hydrogenation of quinolines catalyzed by iridium with chiral ferrocenyloxazoline derived N,P ligands

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 8, Pages 909-912

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404017

Keywords

asymmetric hydrogenation; homogeneous catalysis; N,P ligands; planar chirality; quinolines

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Chiral ferrocenyloxazoline derived N,P ligands are used in the iridium-catalyzed asymmetric hydrogenation of quinolines, and up to 92% ee was obtained. The role of the planar chirality is also studied.

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