Journal
APPLIED SURFACE SCIENCE
Volume 267, Issue -, Pages 62-65Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2012.06.104
Keywords
Organic semiconductor; Phthalocyanine; Interface state; PES
Categories
Funding
- Deutsche Forschungsgemeinschaft [Forschergruppe FOR 1154, KN393/14]
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We compare the electronic properties of the interface between Au(100) and cobalt phthalocyanine (CoPc), fluorinated F16CoPc as well as CuPc using X-ray photoemission spectroscopy and valence band ultra-violet photoemission spectroscopy. Our results show that in addition to the formation of an interface dipole at the interfaces of CoPc and F16CoPc to gold, there is a local charge transfer to the central Co ion, which as a result is reduced to Co(I). (C) 2012 Elsevier B. V. All rights reserved.
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