Journal
APPLIED SURFACE SCIENCE
Volume 286, Issue -, Pages 319-327Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2013.09.079
Keywords
Magnesium alloy; Electroless Ni-P/SiC; Gradient coating; Corrosion resistance; Deposition reaction kinetics
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Funding
- National Natural Science Foundation of China [21073027]
- Fundamental Research Funds for the Central Universities [DUT10LK26]
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In this paper, the protective electroless Ni-P/SiC gradient coatings on AZ91D magnesium alloy substrate were successfully prepared. The prepared Ni-P/SiC gradient coatings were characterized for its microstructure, morphology, microhardness and adhesion to the substrate. The deposition reaction kinetics was investigated and an empirical rate equation for electroless Ni-P/SiC plating on AZ91D magnesium alloy was developed. The anticorrosion properties of the Ni-P/SiC gradient coatings in 3.5 wt.% NaCl solution were evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) studies. The potentiodynamic polarization measurements revealed that the SiC concentration in the bath and heat treatment can influence the corrosion protection performance of electroless deposited Ni-P/SiC gradient coatings. EIS studies indicated that higher charge transfer resistance and slightly lower capacitance values were obtained for Ni-P/SiC gradient coatings compared to Ni-P coatings. The corrosion resistance of the Ni-P/SiC gradient coatings increases initially and decreases afterwards with the sustained increasing of immersion time in the aggressive medium. The electroless Ni-P/SiC gradient coatings can afford better corrosion protection for magnesium alloy substrate compared with Ni-P coatings. (C) 2013 Elsevier B.V. All rights reserved.
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