Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 125, Issue 7, Pages 1169-1172Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2004.03.009
Keywords
antimony pentafluoride; porous aluminum fluoride; difluoromethane
Categories
Ask authors/readers for more resources
A novel fluorination reagent and catalyst, SbF5/PAF (porous aluminum fluoride), was prepared by impregnating SbCl5 into PAF and then treating with anhydrous hydrogen fluoride. The prepared reagent had an excellent catalytic activity in halogen-exchange, and also improved the properties of SbF5, such as hydroscopicity, corrosion, and toxicity. SbF5/PAF was successfully used in organic synthesis as a fluorinating reagent, and a fixed bed catalyst for F/Cl exchange. (C) 2004 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available