Journal
APPLIED SURFACE SCIENCE
Volume 259, Issue -, Pages 486-493Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2012.07.072
Keywords
BaFe12O19; Ni0.8Zn0.2Fe2O4; Polyaniline; Polypyrrole; Electromagnetic properties; In situ polymerization
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Funding
- Spaceflight Foundation of the People's Republic of China [NBXT0002]
- Spaceflight Innovation Foundation of China [NBXW0001]
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The nanocomposite of hard (BaFe12O19)/soft ferrite (Ni0.8Zn0.2Fe2O4) was prepared by the sol-gel process, and then the polyaniline(PANI)/polypyrrole(PPY)-BaFe12O19/Ni0.8Zn0.2Fe2O4 was produced by in situ polymerization method. The structures, morphology and electromagnetic properties of the samples were characterized by various instruments. XRD, TEM, and FTIR analysis indicated that BaFe12O19/Ni0.8Zn0.2Fe2O4 ferrite were homogenously enwrapped by PANI(PPY) coating. The VSM and SDY-4 measurement show that the magnetic properties of the composites decreased with the increase in PANI(PPY) amount, However, the electrical conductivity is on the contrary. The electromagnetic properties of the composites were much better than BaFe12O19/Ni0.8Zn0.2Fe2O4 in the frequency range of 2-15 GHz, which mainly depends on the dielectric loss of PANI(PPY). A minimum reflection loss of the PANI(PPY)-BaFe12O19/Ni0.8Zn0.2Fe2O4 ferrite nanocomposite is -19.7 dB(-21.5 dB) at the frequency of 7.3 GHz (10.7 GHz). (C) 2012 Elsevier B. V. All rights reserved.
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