Journal
CURRENT ORGANIC SYNTHESIS
Volume 1, Issue 3, Pages 211-226Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570179043366765
Keywords
cross-coupling; organosilane; organogermane; siloxane; silanol; germatrane
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The last fifteen years have seen the Pd-catalysed cross-coupling of organosilanes and organogermanes developed to the point where organosilane cross-couplings in particular are emerging as viable and attractive alternatives to the Stille and Suzuki reactions. In this review, the development of these group 14 cross-coupling reactions is overviewed and the current state-of-the-art assessed. Moreover, some mechanistic considerations are presented that, it is hoped, may encourage efforts to overcome remaining challenges in this important area.
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