4.3 Article

A mild ring opening fluorination of epoxide with ionic liquid 1-ethyl-3-methylimidazorium oligo hydrogenfluoride (EMIMF(HF)2.3)

Journal

JOURNAL OF FLUORINE CHEMISTRY
Volume 125, Issue 7, Pages 1127-1129

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2004.02.002

Keywords

fluorohydrin; epoxide ring opening; hydrogen fluoride; ionic liquid

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Ring opening fluorination of epoxides with hydrogen fluoride in ionic liquid 1-ethyl-3-methylimidazorium oligo hydrogenfluoride EMIMF(HF)(2.3) was demonstrated. This ionic liquid released hydrogen fluoride graduately to make mild conditions without oligomerization of epoxides. (C) 2004 Elsevier B.V. All rights reserved.

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