Journal
SUPRAMOLECULAR CHEMISTRY
Volume 16, Issue 5, Pages 337-342Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270410001699346
Keywords
inclusion compounds; kinetics; guest exchange; cyclotriveratrylene
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Inclusion compounds were formed between the host cyclotriveratrylene, H, (2,3,7,8,12,13-hexamethoxy-5,10-dihydro-15H-tribenzo[a,d,g]cyclononene) and the guests carbon tetrachloride, 1,1,1-trichloroethane, 1,1,1-trichloropropane and 1,1,2-trichloroethane. 1 ((HCCl4)-C-.) has guest molecules in channels alternating with channels of host molecules. 2 ((HC2H3Cl3C3H5Cl3)-C-.-C-.) and 3 (H(.)2C(2)H(3)Cl(3)) exhibit a slightly different packing arrangement with one guest molecule in the host cavity and the rest of the guest molecules in channels. The stability and reactivity of these inclusion compounds were investigated.
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