4.3 Article

Complex formation and gelation between copolymers containing pendant azobenzene groups and cyclodextrin polymers

Journal

CHEMISTRY LETTERS
Volume 33, Issue 7, Pages 890-891

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2004.890

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The copolymers of acrylamide and acrylamide with pendant azobenzene (AzBA-AAm) were prepared by radical polymerization. The association constants of trans-AzBA-AAm copolymers with beta-CD are larger than those of cis-AzBA-AAm copolymers. The trans-AzBA-AAm guest copolymer was found to form supramolecular gels with beta-CD-pAA (pAA; poly(allylamine)) host copolymers in water.

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