Journal
ORGANOMETALLICS
Volume 23, Issue 14, Pages 3369-3371Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om0496380
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The monomeric, two-coordinate carbene complex (IPr)CuO-t-Bu (1) (IPr = 1,3-bis(2,6-diisopropylphenyl )imidazol-2-ylidene) reacts readily with silanes such as triethoxysilane, forming a dimeric copper(I) hydride complex (2) with a very short copper-copper distance. Hydrocupration of 3-hexyne by 2 affords a monomeric copper(I) vinyl complex.
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