Journal
TETRAHEDRON LETTERS
Volume 45, Issue 28, Pages 5415-5417Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.05.048
Keywords
hydrosilylation; copper(II) precursor; Cu-H
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Air and moisture stable copper(II) salts can be used to catalyze the hydrosilylation of aromatic ketones. The combination of catalytic amounts of copper(U) acetate or copper(H) acetate monohydrate and BINAP in the presence of organosilanes as the stoichiometric reducing agent generates an active catalyst for the reduction of ketones. (C) 2004 Elsevier Ltd. All rights reserved.
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