4.8 Article

Immobilization of Pd(OAc)2 in ionic liquid on silica:: Application to sustainable Mizoroki-Heck reaction

Journal

ORGANIC LETTERS
Volume 6, Issue 14, Pages 2325-2328

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol049343i

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Palladium acetate was supported on amorphous silica with the aid of an ionic liquid, [bmim]PF6. The immobilized catalyst was highly efficient in promoting the Mizoroki-Heck reaction without a ligand in n-dodecane for at least six reuses, in 89-98% yields. The TON and TOF reached 68 400 and 8000, respectively.

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