Journal
TETRAHEDRON LETTERS
Volume 45, Issue 29, Pages 5677-5679Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.05.092
Keywords
disulfide; disulfide exchange; phosphine-free; rhodium
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A phosphine-free cationic rhodium(I) complex, [Rh(cod)(2)]BF4, is an effective catalyst for disulfide exchange reaction of symmetrical disulfides to unsymmetrical disulfides under inert atmosphere. This reaction could be carried out using unpurified commercial grade solvents under air without decrease of yields and reaction rates. (C) 2004 Elsevier Ltd. All rights reserved.
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