Journal
ORGANOMETALLICS
Volume 23, Issue 15, Pages 3584-3586Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om049741p
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Recently, we reported the first catalytic, intermolecular, anti-Markounikov, hydroarylation of unactivated olefins by a homogeneous, bis-chelating, O-donor Ir(III) complex,(1) (acac)(2)Ir(R)(L), based on the simplest beta-diketonate, acetylacetonate, acac. With the ultimate objective of designing more active catalysts for this potentially useful reaction by structure-function studies, we embarked on developing a rational synthesis of the bis-acac Rh(III) organometallic analogues to the Ir complex. While many tris-acac, late transition metal complexes are known, no rational syntheses of bis-acac, organometallic analogues have been reported. Herein, we report the synthesis and full characterization of the organometallic complex (acac)(2),Rh(Ph)(CH3OH), III, and related analogues. These complexes have all been found to be air and water stable.
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