Journal
ORGANIC LETTERS
Volume 6, Issue 15, Pages 2579-2582Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol049111j
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The temperature dependence of the dissociation of dimers formed from highly stabilized carbon-centered radicals has been examined. Analysis of the data yields the bond dissociation energy (BDE) for the central head-to-head C-C bond in these compounds. For example, for the dimer derived from 3-phenyl-2-coumaranone, BDE is 23.6 kcal/mol and the C-C bond length 1.596 Angstrom, a rather long value for a or bond.
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