Journal
TETRAHEDRON LETTERS
Volume 45, Issue 31, Pages 5991-5993Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.06.046
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Treatment of 2-phenyl-3-vinyl-substituted 2H-azirines with Grubbs' catalyst induces a clean rearrangement and affords products derived from carbon-nitrogen bond cleavage of the 2H-azirine ring. However, when the reaction was carried Out using Wilkinson's catalyst in an alcoholic solvent, the only product obtained in high yield corresponded to an alpha,beta-tinsaturated oxime. (C) 2004 Elsevier Ltd. All rights reserved.
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