Journal
TETRAHEDRON LETTERS
Volume 45, Issue 31, Pages 5999-6002Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.06.040
Keywords
dendrimers; homogeneous catalysis; asymmetric hydrogenations; phosphoramidite ligands
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The axially chiral BICOL backbone was functionalised with two third generation carbosilane dendritic wedges and further elaborated to a phosphoramidite ligand. High enantioselectivities were obtained when these monodentate ligands were applied in the rhodium-catalysed asymmetric hydrogenation of methyl 2-acetamidocinnamate. (C) 2004 Elsevier Ltd. All rights reserved.
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