Investigations on Fe3+ doped polyvinyl alcohol films with and without gamma (γ)-irradiation

This paper deals with the preparation of pure and ferric chloride (FeCl3) doped polyvinyl alcohol (PVA) films by solution casting method. Optical and electrical properties were systematically investigated. We have found the decrease in optical band gap energy of PVA films on doping FeCl3. The optical band gap energy values in the present work are found to be 3.10 eV for pure PVA, 2 eV for PVA:Fe3+ (5 mol%), 1.91 eV for PVA:Fe3+(15 mol%) and 1.8 eV for PVA:Fe3+(25 mol%). Direct current electrical conductivity (sigma) of pure, FeCl3 doped PVA films in the temperature range 70-127 degrees C has been studied. At 387 K dc electrical conductivity of pure PVA film is 5.5795 mu Omega(1) cm(1), PVA:Fe3+ (5 mol%) film is 10.0936 mu Omega(1) cm(1) and gamma-Irradiated PVA:Fe3+ (5 mol%) film for 900 CGY/min is 22.1950 mu Omega(1) cm(1) -1. The result reveals the enhancement of the electrical conductivity with gamma-irradiation. FT-IR study signifies the intermolecular hydrogen bonding between Fe3+ ions of FeCl3 with OH group of PVA. (c) 2009 Elsevier B.V. All rights reserved.