Journal
MACROMOLECULAR SYMPOSIA
Volume 215, Issue -, Pages 295-305Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/masy.200451123
Keywords
ATRP; nanoporosity; ROP; star-shaped polymer
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A unimolecular templating star-shaped polymer with a compatibilizing outer corona, prepared by tandem ROP/ATRP procedures, was dispersed into a thermosetting organosilicate. The organic polymer was thermalized. to leave behind its latent image in the matrix with a pore size that reflected the size of the polymer molecule, and provided the expected reduction in dielectric constant.
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