Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 37, Issue 8, Pages 601-610Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar030061c
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The discovery of short peptide sequences that function as asymmetric catalysts for a variety of reactions is documented. The evolution of the project from an exercise in rational design to an endeavor that combines combinatorial screening with various mechanism-based experiments is presented. The specific development of catalysts for enantioselective acylation, phosphorylation, conjugate addition, and Morita-Baylis-Hillman reactions is described.
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