Journal
POLYMER INTERNATIONAL
Volume 53, Issue 8, Pages 1066-1070Publisher
WILEY
DOI: 10.1002/pi.1492
Keywords
nitroxide-mediated polymerization; open-chain alkoxyamine; nitroxide stability; radical polymerization
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New readily available open-chain alkoxyamines have been synthesized and evaluated as unimolecular initiators for nitroxide-mediated radical polymerization of styrene and n-butyl acrylate. The observed moderate control of polymerization is explained by the low thermostability of the parent nitroxide. (C) 2004 Society of Chemical Industry.
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