Journal
SOLID STATE SCIENCES
Volume 6, Issue 8, Pages 853-858Publisher
ELSEVIER
DOI: 10.1016/j.solidstatesciences.2004.04.001
Keywords
iron(III) carboxylate; open framework; dehydration; Mossbauer; magnetism
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The new compound Fe-III(OH)[C6H2(CO2)(2)(CO2H)(2)].xH(2)O (with x = 0.88) is the first ferric carboxylate with a 3D open structure that has been synthesized up to now. Its structure is built up from chains of octahedra connected by carboxylate ligands; it displays small channels filled by water molecules. The removal of water molecules was studied by Mossbauer spectroscopy which set up defaults of water molecules in the crystal. Magnetic measurements indicate an antiferromagnetic behavior at low temperature, but also a metamagnetic transition for an applied magnetic field larger than 0.5 T. (C) 2004 Elsevier SAS. All rights reserved.
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