Journal
APPLIED SPECTROSCOPY REVIEWS
Volume 49, Issue 4, Pages 271-321Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/05704928.2013.823547
Keywords
ultrasonic nebulization; pneumatic nebulization; electrochemical hydride generation; microwave-induced plasma-optical emission spectrometry; inductively coupled plasma-optical emission spectrometry; chemical vapor generation; electrothermal vaporization; multimode sample introduction; Hydride generation; capillary and microcapillary electrophoresis; slurry sampling; photochemical vapor generation
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Funding
- National Science Centre (NCN), Poland [DEC-2012/06/A/ST4/00382]
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Chemical vapor generation (CVG) offers several significant advantages for analyses, including efficient matrix separation, which often leads to a reduction of interferences and better detection limits; high transport efficiency of analyte into the atomic spectroscopic detector; in some cases, high selectivity to permit differentiation of chemical species of a particular element and enable use of gas-phase separation methods for speciation of some elements. The development of CVG techniques from a Marsh test (arsine generation) to a recent device combining vapor generation with multichannel sample introduction systems and separation or preconcentration techniques at the macro- and microscale for use in optical emission and mass spectrometry is reviewed.
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