Journal
CATALYSIS COMMUNICATIONS
Volume 5, Issue 8, Pages 383-386Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2004.04.006
Keywords
catalytic hydrodehalogenation; palladium/carbon; aromatic halides; aqueous solution
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The hydrodehalogenation of aromatic halides, catalyzed by Pd/C in aqueous solutions, yields arenes in short reaction times at room temperature under normal pressure. The nature of the solvents has an important influence on the reaction rates and the activity of the catalyst. The catalyst shows the highest activity in water. In the hydrodechlorination of 4-chlorohypnone, it was in water that C-Cl bond was easier to be hydrogenated, and in isopropanol that C=O was easier to be hydrogenated. (C) 2004 Elsevier B.V. All rights reserved.
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