4.6 Article

Crystal structure of tris(2,6-di-tert-butyl-4-methylphenolato-O) (tetrahydrofuran-O) erbium toluene solvate

Journal

APPLIED ORGANOMETALLIC CHEMISTRY
Volume 18, Issue 8, Pages 382-383

Publisher

WILEY-BLACKWELL
DOI: 10.1002/aoc.667

Keywords

erbium; aryloxo ligand; crystal structure; X-ray

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A low-coordinate aryloxo erbium complex, [(ArO)(3)Er(THF)](MePh), has been synthesized by the reaction of anhydrous ErCl3 with three equivalents of NaOAr in tetrahydrofuran. The central erbium atom is coordinated by three oxygen atoms of the aryloxo ligands and one oxygen atom of the tetrahydrofuran molecule, resulting in a distorted tetrahedron. Copyright (C) 2004 John Wiley Sons, Ltd.

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