Journal
ORGANIC LETTERS
Volume 6, Issue 16, Pages 2765-2767Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol048994b
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A bis-monopyridyl Wang-type tag was prepared for application in the hydrocarbon/perfluorocarbon phase-switching of substrates/products. This catch-and-release strategy relies on the reversible coordination of the tag to a fluorous copper(II)-carboxylate complex. A hydantoin was prepared in high yield and purity by a four-step protocol where the intermediates were purified by the straightforward liquid/liquid phases-witching process.
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