Journal
ORGANIC LETTERS
Volume 6, Issue 16, Pages 2713-2716Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol049038x
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- NIGMS NIH HHS [GM 65338] Funding Source: Medline
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The transannular cyclization of an enantioenriched cyclodecenyl radical proceeds in a 5-exo fashion to produce scalemic bicyclo[5.3.0]decanes. This cyclization is notable because it demonstrates chirality transfer through conformational memory of an unstabilized secondary radical.
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