4.4 Article

An expeditious entry to carbohydrate derived enynes and ene-diynes via Sonogashira coupling of halo-exo-glyeals

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 33, Pages 6307-6310

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.06.079

Keywords

exo-glyeals; Sonogashira; enyne; ene-diyne

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Sonogashira coupling of bromo or iodo-exo-glycals, readily prepared from 1-exo-methylene furanoses and pyranoses, provides an efficient entry to furanose- and pyranose-derived enyne and ene-diyne moieties found in biologically relevant structures. (C) 2004 Elsevier Ltd. All rights reserved.

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