4.5 Article

Pd/C-catalyzed transfer reduction of aryl chlorides with sodium formate in water

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2004, Issue 16, Pages 3404-3407

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200400258

Keywords

reductive dechlorination; palladium; catalysis; sodium formate; aryl chlorides

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Sodium formate catalytic transfer reduction, in the presence of palladium on carbon, accomplishes not only the rapid dehalogenation of aromatic chlorocarbons in water at room temperature, but also the reduction of the aromatic moieties to alicyclic rings at 100degreesC. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

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