Journal
TETRAHEDRON
Volume 60, Issue 34, Pages 7277-7285Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.06.019
Keywords
metallopolymer; poly(caprolactone); beta-diketonate; europium
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Dibenzoylmethane (dbm) initiators with one and two alcohol sites were used to generate dbm end-functionalized and dbm-centered poly(epsilon-caprolactone) macroligands (dbmPCL and dbmPCL(2)) with low polydispersities (similar to1.1). Chelation of polymeric ligands to metal ions (Eu3+, Fe3+, Ni2+ and Cu2+) produced metal-centered star polymers, which were characterized by UV-vis and fluorescence spectroscopy, as well as gel permeation chromatography. (C) 2004 Elsevier Ltd. All rights reserved.
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