Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 69, Issue 17, Pages 5660-5667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo049359m
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Phosphoramidite ligands, based on ortho-substituted biphenols and a chiral amine, induce high enantioselectivities (ee's up to 99%) in the copper-catalyzed conjugate addition of dialkylzinc reagents to a variety of Michael acceptors. Particularly, the best reported ee's were obtained for acyclic nitroolefins.
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