Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 11, Pages 1263-1266Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404080
Keywords
asymmetric catalysis; chiral bisphospholanes; enantioselective hydrogenation; homogeneous catalysis; P ligands; rhodium
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The new - commercially in multi-kg quantities available - chiral bisphospholane ligand, catA-Sium(R) M, has been successfully used in the Rh(I)catalysed enantioselective hydrogenation of itaconic acid derivatives. Chiral beta-substituted succinic acid derivatives were produced in good to excellent enantioselectivities. Turnover frequencies by up to 40,000 h(-1) have been achieved.
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