Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 9, Pages 1010-1013Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2004.07.001
Keywords
cycloaddition; endohedral metallofullerenes; fullerenes; fulleropyrrolidines
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Azomethine ylides, generated from the reactions of different aldehydes (RCHO) 1a-d with sarcosine, reacted with endohedral metallofullerenes M@C-82 (M = Gd, Y) affording multi-substituted metallofulleropyrrolidines. The formation of these derivatives was confirmed by matrix assisted laser desorption/ionization (MALDI) time-of-flight (TOF) mass spectrometry and some of them were isolated by recycling HPLC. (C) 2004 Elsevier B.V. All rights reserved.
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