Journal
RUSSIAN CHEMICAL BULLETIN
Volume 53, Issue 9, Pages 1949-1953Publisher
SPRINGER
DOI: 10.1007/s11172-005-0054-5
Keywords
sandwich compounds; arene complexes; rhodium; iridium
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The dicationic arene complexes [CpM(arene)](BF4)(2) (arene = C6H6, 1,3,5-C6H3Me3, or C6Me6) were synthesized by the reactions of the solvated complexes [CpM(MeNO2)(3)](BF4)(2) (M = Rh, Ir) with benzene and its derivatives. The solvated complexes were generated in situ by abstraction of I- from [CPMI2](2) with AgBF4. A procedure was developed for the synthesis of the iodide [CpRhI2](2) based on the reaction of the cyclooctadiene derivative CpRh(1,5-C8H12) with I-2. The structure of the [CpRh(C6Me6)](BF4)(2) complex was established by X-ray diffraction analysis.
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