Journal
RUSSIAN CHEMICAL BULLETIN
Volume 53, Issue 9, Pages 2008-2012Publisher
SPRINGER
DOI: 10.1007/s11172-005-0063-4
Keywords
bis(diphenylphosphoryl)diphenylphosphinomethane; tris(diphenlylphosphoryl)methane; 1,1,1-tris(diphenylphosphino methyl)pro pane; 1,1,1-tris(diphenylphosphorylmethyl)propane
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The reaction of 1,1,1-tris(chloromethyl)propane with diphenylphosphine under phase-transfer conditions afforded 1,1,1-tris(diphenylphosphinomethyl)propane, whose oxidation gave a previously unknown representative of trigonal tris(phosphine oxides), viz., stable 1,1,1-tris(diphenylphosphorylmethyl)propane. Its analogs, viz., bis(diphenylphosphoryl)diphenylphosphinomethane and tris(diphenylphosphoryl)methane, are unstable in air and decompose with the cleavage of the P-C bond.
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