4.6 Article

Bright persistent ceramic phosphors of Ce3+-Cr3+-codoped garnet able to store by blue light

Journal

APPLIED PHYSICS LETTERS
Volume 104, Issue 10, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.4868138

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Funding

  1. JSPS KAKENHI [25810136, 23350099]
  2. JST, A-STEP
  3. Grants-in-Aid for Scientific Research [23350099, 25810136] Funding Source: KAKEN

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We have developed bright persistent phosphors of Ce3+-Cr3+-doped Y3Al5-xGaxO12 (x = 2.5, 3, 3.5) ceramics with green luminescence (Ce3+:5d -> 4f) via blue-light excitation. The persistent luminance value 5 min after ceasing blue-light excitation for the Ce3+-Cr3+-doped Y3Al2Ga3O12 sample is approximately 3900 times higher than that for a Ce3+-doped Y3Al2Ga3O12 sample and better than that from compact SrAl2O4: Eu2+-Dy3+ powders. The results are consequences of efficient carrier trap formation and effective excitation of the interior of the translucent ceramic samples. A series of Ce3+-Cr3+-doped garnet materials is the best candidate for the persistent phosphor under white-light emitting diode (LED) illumination consisting of blue LEDs and visible phosphors. (C) 2014 AIP Publishing LLC.

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