Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 108, Issue 35, Pages 13062-13065Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp047194f
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Tetrahedrally coordinated aluminum in MFI zeolite frameworks controls the mechanism of intracrystalline mesopore formation by desilication in alkaline medium. The optimal molar Si/Al ratio in the range of 25-50 enables a controlled mesoporosity development with preserved crystalline and acidic properties, potentially leading to a more efficient zeolite utilization by improved diffusion characteristics.
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