Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 69, Issue 18, Pages 5813-5837Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0491004
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The diversity of mechanisms for enantiodiscrimination and of bond types that can be formed make Pd-catalyzed asymmetric allylic alkylation a powerful key step for simplification of synthetic strategy to complex molecular targets. Using a wide range of different classes of compounds including alkaloids, polyhydrofurans, nucleosides and carbanucleosides, cyclohexitols and cyclopentitols, chromanes, cyclopentanoids, amino acids, barbiturates, etc., novel synthetic strategies emerge that provide short efficient asymmetric syntheses.
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