4.4 Article

Proline-catalyzed ketone-aldehyde aldol reactions are accelerated by water

Journal

SYNLETT
Volume -, Issue 11, Pages 1891-1896

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2004-831296

Keywords

aldehydes; aldol reactions; ketones; proline catalysis; water

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Proline-catalyzed aldol reactions between acetone or 4-thianone and different aldehydes are accelerated by addition of 110 equivalents of water to the reaction medium, allowing stoichiometric aldol reactions to proceed at acceptable rates.

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