Journal
INORGANICA CHIMICA ACTA
Volume 357, Issue 12, Pages 3493-3502Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2004.01.048
Keywords
salcyen; titanium; complexes; asymmetric
Categories
Ask authors/readers for more resources
Titanium complexes based on the (R,R)-N,N'-bis(2-hydroxy-3-functionalised-benzylidene)-1,2-diaminocyclohexane ligand and containing either chloro or bridged oxo co-ligands have been prepared, subjected to single crystal X-ray analysis and examined as pre-catalysts for the asymmetric phospho-aldol (PA) reaction. Catalysis does take place although at a much slower rate than with related aluminium complexes and then only to afford racemic products; significant observations that lead to an important design point in PA pre-catalysts. (C) 2004 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available