4.8 Article

LiNiPO4-LiCoPO4 solid solutions as cathodes

Journal

JOURNAL OF POWER SOURCES
Volume 136, Issue 1, Pages 150-153

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2004.05.017

Keywords

cathode; Li-ion batteries; olivine; phosphates; solid solution

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LiNiPO4-LiCOPO4 solid solutions were investigated as potential cathodes for use in Li-ion batteries. Cyclic voltammetry and discharge curves reveal that the discharge capacity of the LiNiPO4-LiCOPO4 solid solutions is associated entirely with the Co3+/Co2+ redox couple at a potential of 4.7-4.8 V The effect of Ni is to reduce the length of the 4.7-4.8 V plateau. (C) 2004 Elsevier B.V. All rights reserved.

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