Journal
ORGANIC LETTERS
Volume 6, Issue 19, Pages 3357-3359Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol048695m
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The axially chiral bisphosphine ligand, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyI (binap), was supported on a polystyrene-poly(ethylene glycol) copolymer (PS-PEG) resin and was used successfully for the rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones in water.
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