Journal
TETRAHEDRON LETTERS
Volume 45, Issue 39, Pages 7235-7238Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.08.029
Keywords
asymmetric catalysis; aldehydes; ketones; alpha-aminoxylation; pyrrolidine sulfonamide
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A novel, pyrrolidine sulfonamide-based organocatalyst has been developed and used to catalyze direct, efficient alpha-aminoxylation reactions of aldehydes and ketones with excellent regio- and en antioselectivities. Unlike L-proline, the new catalyst exhibits high activity and enantioselectivity when used in a variety of organic solvents. (C) 2004 Elsevier Ltd. All rights reserved.
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